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The exosphere (Ancient Greek: ἔξω éxō "outside, external, beyond", Ancient Greek: σφαῖρα sphaĩra "sphere") is a thin, atmosphere-like volume surrounding a planet or natural satellite where molecules are gravitationally bound to that body, but where the density is so low that the molecules are essentially collisionless. In the case of bodies with substantial atmospheres, such as Earth's atmosphere, the exosphere is the uppermost layer, where the atmosphere thins out and merges with outer space. It is located directly above the thermosphere. Very little is known about it due to lack of research. Mercury, the Moon and three Galilean satellites of Jupiter have surface boundary exospheres, which are exospheres without a denser atmosphere underneath. The Earth's exosphere is mostly hydrogen and helium, with some heavier atoms and molecules near the base.

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